Spider - Manis one of those superheroes who do his best to keep his identity element a secret for the safety of his have it off 1 , but in Sam Raimi’sSpider - Mantrilogy , the villain that Tobey Maguire ’s Spider - Man total across ended up pick up his identity in different ways . After a long process with a lot of obstacle , Spider - Man lastly made his big screen entry in 2002 in Sam Raimi’sSpider - Man , which research the character ’s origin story and saw him battle his very first enemy : Norman Osborn ( Willem Dafoe ) , who the audience see become the Green Goblin after an experimentation break down abominably awry .

The achiever ofSpider - Manmade way forSpider - Man 2 , one of the dependable superhero motion picture ever made . In it , Spider - Man faced Doctor Otto Octavius ( Alfred Molina ) , who after an accident during his latest project , ended up becoming the villain Doctor Octopus . Meanwhile , Peter ’s best supporter Harry Osborn ( James Franco ) started his own villainous course , which arrive at its peak inSpider - Man 3 . Along with Harry , Spider - Man 3also regard the arrival of villain Sandman ( Thomas Haden Church ) and Eddie Brock ( Topher Grace ) , who bonded with the Venom symbiote , and just like the Green Goblin and Doc Ock , theyall check Spider - Man ’s identity , as he either unmasked himself or they were simply at the right place at the right fourth dimension for the big reveal . Here ’s how every baddie in Raimi’sSpider - Mantrilogy discovered his personal identity .

Norman Osborn/Green Goblin

Norman Osborn was the father of Peter ’s secure friend , Harry , and he was a scientist and the beginner and owner of Oscorp , a multi billion - dollar mark multinational corp . Norman wanted to secure an crucial military contract bridge , so he try out on himself with a performance - enhancing chemical that was in reality quite mentally ill , and the experiment did n’t go well . The experimentation kill Norman ’s supporter and made him go mad , develop a villainous alter ego that became known as the Green Goblin . After killing the members of Oscorp ’s dining table , the Green Goblin offered Spider - Man to join his side , but as the latter reject , their contention began . In one of their fights , the Green Goblin thresh Spider - Man ’s sleeve , and that seemingly insignificant injury gave his identity operator away .

After their fight , Peter devolve home for Thanksgiving dinnerwith Aunt May , who invited Mary Jane ( Kirsten Dunst ) , Harry , and Norman . During dinner party , Aunt May pointed out that Peter ’s arm was bleeding , with Peter saying that he “ stepped off a American Stock Exchange and got clipped by one of those cycle courier ” . Norman straight off recognize the injury and leave , but the Green Goblin used this raw find to place Spider - Man , agnise that the only room to defeat him was by attacking his loved ones . In the original timeline ( that is , not the one that continued inSpider - Man : No Way Home ) , the Green Goblin was spike by his glider , and Spider - Man took his consistency to the Osborn house , where Harry witness him .

Doctor Octopus

Spider - Man 2introduced Doctor Otto Octavius , a nuclear scientist mold on behalf of Oscorp and Peter ’s part framework . Oscorp , now led by Harry , was financing Octavius ’ nuclear fusion reaction power project , but a public demo went horribly wrong . so as to handle risky fabric , Octavius wear a harness of machinelike tentacle arms with artificial intelligence information , but a exponent spike get the spinal fusion reactor to destabilise , and as Octavius refused to shut it down , it killed his married woman and burn the inhibitor flake that blocked the arms from his skittish scheme , thus now give them ascendancy of Octavius , who decided to re - test the experimentation . The now - called “ Doctor Octopus ” need the isotope tritium to fire his reactor , so he made a deal with Harry : he would give him the tritium , and Doc Ock would give Harry Spider - Man .

In ordering to push Peter to discover Spider - Man ’s identity , Doc Ock kidnapped Mary Jane and took her to his lair . Once there , Spider - Man uncloak himself in front of Doc Ock to sway him to hold on the atomic nuclear reactor , which was assign the whole metropolis in danger . In a second of full consciousness , Octavius control the tentacle to obey him and prefer to give him in society to destroy the reactor , while Spider - Man saved Mary Jane , who at that moment also memorize his true individuality .

Harry Osborn/New Goblin

As Harry saw Spider - Man go away Norman ’s utter consistency at his house , he charge the web - slinger for his father ’s last and affirm vengeance against him . Harry really instruct Spider - Man ’s identity before his transmutation into a baddie , as it chance inSpider - Man 2and he became the New Goblin inSpider - Man 3 . Doctor Octopus fill his part of the architectural plan with Harry and delivered him an unconscious Spider - Man , who Harry unmasked before kill him as he had planned , but was genuinely shocked to see that his best friend was behind the mask .

At the end ofSpider - Man 2 , Harry found his don ’s Green Goblin equipment and became New Goblin inSpider - Man 3 , where he campaign Spider - Man , but their first fight consecrate Harry partial memory loss . Harry eventually recovered and continued messing with Peter , but after his Samuel Butler let on to him that Spider - Man was n’t Norman ’s murderer and his father was actually impaled by his own glider , Harry unite Spider - Man ’s fight against Venom and sacrifice himself to redeem Peter and MJ .

Related : Raimi ’s Spider - Man Left Behind A Big Harry Osborn Question

Spider-Man Noir

Eddie Brock/Venom

InSpider - Man 3 , Peter met Eddie Brock , a fellow photographer who promptly became his rival at theDaily Bugle , but was exposed by Peter for create fake incriminating images of Spider - Man . This was the trigger for Eddie ’s hate of Peter , and he learned that he and Spider - Man were the same person thanks to a shell of being in the veracious shoes at the right meter . After being fired from theDaily Bugle , Eddie went to a Christian church to let all his feelings out , including how much he wanted Peter dead . Unbeknownst to him , Spider - Man was at the church building too , struggling to get the Venom symbiote off of him and hitting the church ’s bells , discovering that high up - pitched sound weakened the symbiote . Eddie hear the bell and the struggle and followed the sound , and was surprised to see an unmasked Spider - Man – and , as a bonus , he bonded with the Venom symbiote . for hurt Peter , Eddie kidnapped MJ , and after Peter assort the symbiote from him , Eddie died when he taste to save the symbiote from a pumpkin dud .

Sandman

Flint Marko was a small - time thug who scarper prison , and after visiting his sickish girl , he fell into an data-based particle gas pedal that coalesce his body with sand . This yield him the power to hold in sand and rectify his body with it , becoming Sandman . After his first fight with Spider - Man , he was convert by Brock to team up up to pop the web - slinger , and after Venom and Brock ’s defeat , he see an unmasked Spider - Man . Marko then say Peterthe truth about Uncle Ben ’s deathand his involvement in it , confessing it was an chance event and he did n’t intend to wipe out him . Peter forgave Marko , who then turned into gumption and flew forth in the breeze .

Ben Affleck as Christian drumming his hand on the table while talking to Cynthia Addai-Robinson’s Marybeth in The Accountant 2

In a dusty landscape Finn stares out into the distance in Star Wars: The Force Awakens

Green goblin Tobey maguire spiderman eddie brock venom

Green Goblin with his helmet off in Spider-Man No Way Home.

Doctor Octopus (Alfred Molina) sacrifices himself spider-man 2

Spider-Man 3 Harry Osborn New Goblin

Spider-Man 3 Topher Grace as Eddie Brock

Sandman Spiderman 3 Tobey maguire peter parker

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